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Diamond, the hardest
substance known to man, and
a precious
mineral, is obtained from
nature. Diamond is not an
average substance. Their
extreme hardness, resistance
to tarnishing, exquisite
clarity and clean facelting
make them all above the rest
of minerals. Diamonds
demonstrate distinctive
properties of which you may
not be aware: e. g, Diamonds
are excellent conductors of
heat, but poor conductors of
electricity. The heat
conductivity of diamond is
so extraordinary that modern
tests to determine whether a
gem is genuine diamond or
fake, is based on
measurement of the gem’s
heat conductivity.
Diamonds play another
important role in modern
industrial society: an
industrial workhorse. The
unusual properties of
diamond makes it
technologically very
important. Because of its
extreme hardness, diamonds
are excellent for surgical
cutting tools and coatings
on cutting tools for
drilling, mining, and
industrial productions. A
rapidly emerging technology
centers on thin films of
diamond. Diamond films have
been marketed on tweeters in
stereo speakers and as
scratchproof coatings on
watches. Diamond coated
windows for infra-red
scanning systems and light
filtering masks are also on
the market. Diamonds offer
promise for new electronic
materials.
Diamond is pure natural
carbon with atoms organized
in close packed cubic
arrangement that gives the
stones their extreme
hardness. Under normal
conditions, graphite is the
most stable form of carbon,
because the bonds in
graphite are stronger. In
part this stability can be
attributed to resonance.
Having the double bond
character spread evenly
throughout the entire
structure adds extra
stability to graphite. When
several different forms of
matter with the same
compositions exist, the most
stable structure is called
the thermodynamically
favourable form. Under the
usual conditions of
atmospheric pressure and
room temperature, the most
stable or thermodynamically
favourable form of carbon is
graphite.
However, at high pressure,
diamond becomes more stable
than graphite. We can
understand why the preferred
arrangement of atoms may
change with pressure. On
average the carbon atoms in
diamond are closer together
than the carbon atoms in
graphite. As a result
diamonds are more dense
(that is, more mass in a
given volume) than graphite.
When a piece of graphite is
subjected to high pressure,
the external forces compress
the graphite or push the
carbon atoms closer
together. Under these
conditions it is more
favourable for the carbon
atoms to rearrange
themselves into diamond
structure. If graphite is
squished (very high pressure
is applied) then the
graphite will be transformed
into diamond.
Diamonds are formed deep
inside the earths interior
where crushing pressure and
blistering heat work
together for a long period
of time to create the
diamond lattice. Although
scientists have puzzled long
about how diamonds are
transported to earth’s
surface, a recent discovery
of diamonds in Canada may
have shed some light on this
issue. Scientists now
believe that, narrow
volcanic pipes running down
into the earths interior
allows diamonds to be
transported via violent
eruptions to the earth’s
surface. The eruptions were
so fast and so violent that
diamonds were coughed
straight to the surface. It
is believed the time taken
to form a natural diamond is
approximately billions of
years.
Synthetic diamonds on the
other side can be formed in
much the same way as natural
diamonds. Graphite is heated
to temperatures exceeding
15000C at about 60,000
atmospheres of pressure
(that is a pressure 60,000
times greater than the
normal pressure exerted by
our atmosphere). Even at
these temperatures and
pressures, diamond formation
is not easy. Addition of
small amounts of the
metallic elements, iron or
nickel speeds up the
reaction. Why are the metals
added? The role of the
metallic additives is to
reduce the amount of energy
needed to form diamond from
graphite.
The metal in reaction with
the lower activation energy
acts as a catalyst in the
reaction. A catalyst is a
substance that affects the
rate of a reaction without
being consumed by the
overall reaction process.
Chemistry says that,
catalysts do not affect the
thermodynamics of the
reaction; rather they affect
the kinetics. In diamond
formation, the metal
catalysts are trapped in the
diamond lattice as it is
formed. This is why many
synthetic diamonds are
coloured, while naturally
occurring diamonds, which
lack in impurities are
colourless. So, natural
diamonds are free of any
impurities compared to
synthetic diamonds, and
hence costly and more
durable.
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